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The study of ultrafast reactions: femtochemistry. Bounce mechanisms, stripping and with complex formation. Angular distribution and of the speed of the reaction products. The experimental study of molecular collisions. Collision theory: sphere of collision, shock section, shock energy and steric factor. Dependence of the reaction rate from the temperature.
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Einstein coefficients, spontaneous emission and stimulated emission. Franck-Condon principle and vibronic transitions. Electronic transitions in diatomic and polyatomic molecules. Vibro-rotational spectra of two-, and triatomic molecules.Įlectronic spectroscopy. Application of the anharmonic oscillator model - Normal modes of a polyatomic system and vibrational spectra.
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Vibrational spectra of diatomic molecules and selection rules according to the harmonic oscillator model. Classification of molecules from a rotational standpoint and their spectra: linear rotators, symmetrical oblates and prolates, spherical, asymmetrical. energy levels rotational and rotational spectra of diatomic molecules.
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Born-Oppenheimer approximation for spectroscopy. Interaction electromagnetic radiation with matter. II - Light-matter interaction and molecular spectroscopy.īasic principles of molecular spectroscopy. Introduction to electronic structure of solids. Experimental evidence of the existence of molecular orbitals. Extension of the Hückel method to compounds containing heteroatoms.
#Chimica fisica atkins de paula pdf pdf#
Calculation of charge distributions for a π system. Cf Solucionario Ejercicios De FisicoQuimica 3 5 V 1mol S Mol Chimica Fisica Atkins De Paula Pdf physical chemistry by david w ball selectedworks april 29th, 2018 - intended for the year long calculus based physical chemistry course for science and. Orbital σ and π - Application of the method of molecular orbitals aufbau - Electronic configuration and properties of diatomic homonuclear molecules. Diatomic molecules with more than one electron. Molecular orbitals of bonding and antibonding. Overlap integrals, Coulomb and exchange and their contribution to the stability of the chemical bond. The molecular orbital method and application to the hydrogen molecule ion. The chemical bond and diatomic molecules. Independent Electron Theory for complex atoms. Variational principle and mean field theory for atoms with more electrons.
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